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[资源] Chem. Rev.最新综述：超分子聚合物张希院士出品

本综述全面介绍了超分子聚合物的驱动力，支化和超支化拓扑结构的超分子聚合物，控制超分子聚合物的新策略，超分子聚合物的表征，及超分子的应用等，对超分子聚合物做了全面的总结。

Supramolecular Polymers: Historical Development, Preparation,Characterization, and Functions共35页引文297篇
Liulin Yang , Xinxin Tan , Zhiqiang Wang , and Xi Zhang *
Key Laboratory of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China
DOI: 10.1021/cr500633b
Supramolecular polymers, originating from the integration of polymer science and supramolecular chemistry, have been a rapidly developing interdisciplinary research area. In the broad sense, the term “ supramolecular polymers ” can be de ﬁ ned as any type of assembly formed from one or more molecular components via reversible bonds.However, to avoid confusion, a limited de ﬁ nition regarding supramolecular polymers as “ polymeric arrays of monomeric units that are held together by highly directional and reversible noncovalent interactions, resulting in polymeric properties in solution and bulk ” is more explicit and recommended. A variety of noncovalent interactions (e.g., multiple hydrogen bonding, metal coordination, host − guest interactions, and aromatic stacking) have been employed as driving forces to construct supramolecular polymers.

Table of Contents
1. Introduction
2. Driving Forces for Supramolecular Polymers
2.1. Multiple Hydrogen Bonds
2.1.1. Hydrogen-Bonding Arrays
2.1.2. Hydrogen-Bonded Supramolecular Polymers
2.2. Metal-Coordination Bonds
2.2.1. Ligands and Metal Ions
2.2.2. Counterions
2.2.3. Stoichiometric Ratio
2.3. Host–Guest Interactions
2.3.1. Cyclodextrin-Based Supramolecular Polymers
2.3.2. Cucurbit[8]uril-Based Supramolecular Polymers
2.3.3. Crown Ether-Based Supramolecular Polymers
2.3.4. Calixarene-Based Supramolecular Polymers
2.3.5. Pillararene-Based Supramolecular Polymers
2.4. Aromatic Donor–Acceptor Interactions
2.5. Multiple Driving Forces
3. Supramolecular Polymers with Branch-like and Hyperbranch-like Topology
3.1. Supramolecular Dendrimers
3.2. Supramolecular Hyperbranched Polymers
4. New Strategies for Controllable Supramolecular Polymerization
4.1. Polymerization of a Supramonomer
4.2. Self-Sorting Controlled Supramolecular Polymerization
4.3. Stimulus-Controlled Supramolecular Polymerization
4.4. Living Supramolecular Polymerization
5. Characterization of Supramolecular Polymers
5.1. Size Exclusion Chromatography
5.2. Viscometry
5.3. NMR Spectroscopy
5.4. AFM-Based Single-Molecule Force Spectroscopy
5.5. Light Scattering
5.6. Small-Angle Neutron Scattering
5.7. Asymmetric Flow Field-Flow Fractionation
5.8. Other Methods
6. Application of Supramolecular Polymers
6.1. Optoelectronic Materials
6.2. Supramolecular Self-Healing Materials
6.2.1. Self-Healing Materials Based on Multiple Hydrogen Bonding
6.2.2. Self-Healing Materials Based on Metal-Coordination Bonding
6.2.3. Self-Healing Materials Based on π–π Interactions
6.3. Biomedical Applications
7. Conclusions and Outlook

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