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[资源] ★★★★★★2014书籍超级帖九三七《多相反应器设计》2014最新书籍

书名Design of Multiphase
Reactors
作者Vishwas Govind Pangarkar
Formerly Professor of Chemical Engineering and Head of Chemical
Engineering Department
Institute of Chemical Technology
页数535
出版社wiley
index.
ISBN 978-1-118-80756-9 (hardback
目录
Foreword xv
Preface xvii
1 E volution of the Chemical Industry and Importance of
Multiphase Reactors 1
1.1 Evolution of Chemical Process Industries, 1
1.2 Sustainable and Green Processing Requirements in the Modern
Chemical Industry, 4
1.3 Catalysis, 9
1.3.1 Heterogeneous Catalysis, 11
1.3.2 Homogeneous Catalysis, 16
1.4 Parameters Concerning Catalyst Effectiveness in Industrial
Operations, 17
1.4.1 Chemoselectivity, 19
1.4.2 Regioselectivity, 19
1.4.3 Stereoselectivity, 19
1.5 Importance of Advanced Instrumental Techniques in Understanding
Catalytic Phenomena, 20
1.6 Role of Nanotechnology in Catalysis, 21
2 Multiphase Reactors: The Design and Scale-Up Problem 30
2.1 Introduction, 30
2.2 The Scale-Up Conundrum, 31
2.3 Intrinsic Kinetics: Invariance with Respect to Type/Size of Multiphase
Reactor, 34
2.4 Transport Processes: Dependence on Type/Size of Multiphase Reactor, 34
2.5 Prediction of the Rate-Controlling Step in the Industrial
Reactor, 35
2.6 Laboratory Methods for Discerning Intrinsic Kinetics of Multiphase
Reactions, 35
2.6.1 Two-Phase (Gas–Liquid) Reaction, 35
2.6.2 Three-Phase (Gas–Liquid–Solid) Reactions with Solid Phase
Acting as Catalyst, 41
Nomenclature, 44
References, 45
3 Multiphase Reactors: Types and Criteria for Selection for a
Given Application 47
3.1 Introduction to Simplified Design Philosophy, 47
3.2 Classification of Multiphase Reactors, 48
3.3 Criteria for Reactor Selection, 48
3.3.1 Kinetics vis-à-vis Mass Transfer Rates, 49
3.3.2 Flow Patterns of the Various Phases, 50
3.3.3 Ability to Remove/Add Heat, 50
3.3.4 Ability to Handle Solids, 53
3.3.5 Operating Conditions (Pressure/Temperature), 54
3.3.6 Material of Construction, 54
3.4 Some Examples of Large-Scale Applications of Multiphase Reactors, 55
3.4.1 Fischer–Tropsch Synthesis, 55
3.4.2 Oxidation of p-Xylene to Purified Terephthalic Acid for
Poly(Ethylene Terephthalate), 67
Nomenclature, 80
References, 81
4 T urbulence: Fundamentals and Relevance to Multiphase
Reactors 87
4.1 Introduction, 87
4.2 Fluid Turbulence, 88
4.2.1 Homogeneous Turbulence, 89
4.2.2 Isotropic Turbulence, 90
4.2.3 Eddy Size Distribution and Effect of Eddy Size on
Transport Rates, 90
Nomenclature, 91

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