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[资源] chemical reviews11.17 新鲜在线：Alloy Negative Electrodes for Li-Ion Batteries

Alloy Negative Electrodes for Li-Ion Batteries
M. N. Obrovac*,† and V. L. Chevrier‡
（59页 533篇文献）

CONTENTS
1. Introduction A
2. Key Parameters of Alloy Anode Performance C
2.1. A Cell-Based Model for Comparing Anode Performance C
2.2. Full Cell Volumetric Energy Comparison of the Active Elements F
2.3. Electrode Porosity, Irreversible Capacity, and Coulombic Efficiency G
3. Fundamentals of Li Insertion in Metals and Alloys G
3.1. The Active Elements G
3.1.1. Hydrogen and the Alkali Metals H
3.1.2. The Alkaline Earth Metals H
3.1.3. The Transition Metals I
3.1.4. The p-Block Elements J
3.2. Selective Formation of Li−M Equilibrium Phases N
3.3. Volume Expansion during Lithiation N
3.4. Effect of Two-Phase Regions on Cycle Life O
3.5. Ability of DFT To Predict Alloy Voltages O
3.6. The Electrochemistry of Silicon Q
3.6.1. The Electrochemistry of Bulk Silicon Q
3.6.2. The Electrochemistry of Nanosized Silicon T
3.6.3. The Electrochemistry of Thin Film Silicon T
3.7. Alloys of the Active Elements U
3.7.1. Active/Active Alloys V
3.7.2. Active/Inactive Alloys AC
4. Binders, Surface Coatings, and Electrolytes AH
4.1. Binders AH
4.2. Surface Coatings AJ
4.3. Electrolytes and Additives AK
4.3.1. Electrolytes for Silicon Alloys AK
4.3.2. Electrolytes for Tin Alloys AL
5. Evaluation of Alloy Cycling Performance in Cells and Coatings AL
5.1. Half-Cells AM
5.1.1. Half-Cell Cycling Using Constant Voltage Limits AM
5.1.2. Half-Cell Cycling Using Constant Capacity Limits AM
5.1.3. Differential Capacity Analysis AN
5.2. Symmetric Cells AN
5.3. Full Cells AN
5.4. Impedance Analysis AO
5.5. Acoustic Emission Analysis AP
5.6. Dilatometry AP
5.7. Isothermal Calorimetry AQ
6. Thermal Stability of Alloy Negative Electrodes AQ
6.1. Reactivity of Alloy Anodes As Compared To Graphite AR
6.2. Impact of Solvent and Salt on Alloy Thermal Stability AR
6.3. Impact of Surface Area on Alloy Thermal Stability AR
7. Implementation in Commercial Cells AS
7.1. Irreversible Capacity Management AS
7.2. Coating Design for Commercial Cells AS
7.3. Some Industrially Developed Alloy Materials AT
7.3.1. Sn−Co−C Alloys AT
7.3.2. SiO-Based Electrodes AV
7.3.3. Si−Metal Alloys AX
8. Concluding Remarks AX
Author Information AY
Corresponding Author AY
Notes AY
Biographies AY
Acknowledgments AY
References AY

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2014-11-18 08:34:00, 3.27 M