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[交流] 一篇Li-S电池文献交流

The Fermi energy of Li is higher than the low unoccupied molecular orbital of the commonly used liquid electrolytes. As a result, the electrolytes can be reduced on the surface of the Li anode to form a solid electrolyte interphase (SEI) layer, causing a remarkable irreversible capacity loss and low deposition efficiency of Li upon charging.For practical Li-S batteries, this condition may lower the energy output of the system by requiring an excessive amount of Li to pair with S cathode.
锂的费米能高于一般所用的液体电解质低空置分子轨道。为什么会导致电解质在锂阳极表面形成固态电解质中间层,电解质减少?
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