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Angew. Chem. Int. Ed.最新综述：氧化物表面的共价表面改性
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Covalent Surface Modification of Oxide Surfaces 共35页 引文208篇 Sidharam P. Pujari, Luc Scheres, Antonius T. M. Marcelis, and Han Zuilhof* Laboratory of Organic Chemistry, Wageningen University P.O. Box 26, 6703 HB Wageningen (The Netherlands) E-mail: han.zuilhof@wur.nl Dr. L. Scheres Surfix B.V. Dreijenplein 8, 6703 HB Wageningen (The Netherlands) Prof. Dr. H. Zuilhof Department of Chemical and Materials Engineering King Abdulaziz University Jeddah (Saudi Arabia) From the Contents 1. Introduction 6323 2. Silanes 6324 3. Phosphonates 6328 4. Carboxylates 6332 5. Catechols 6335 6. Alkenes and Alkynes 6339 7. Amines 6345 8. Other types of monolayers 6348 9. Summary and Outlook 6349 The modification of surfaces by the deposition of a robust overlayer provides an excellent handle with which to tune the properties of a bulk substrate to those of interest. Such control over the surface properties becomes increasingly important with the continuing efforts at downsizing the active components in optoelectronic devices, and the corresponding increase in the surface area/volume ratio. Relevant properties to tune include the degree to which a surface is wetted by water or oil. Analogously, for biosensing applications there is an increasing interest in so-called “romantic surfaces”: surfaces that repel all biological entities, apart from one, to which it binds strongly. Such systems require both long lasting and highly specific tuning of the surface properties. This Review presents one approach to obtain robust surface modifications of the surface of oxides, namely the covalent attachment of monolayers.  |
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