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[资源] 最新一篇关于石墨烯支撑的纳米电催化剂合成、应用的综述Chemical Reviews

Graphene-Supported Nanoelectrocatalysts for Fuel Cells: Synthesis,
Properties, and Applications
Minmin Liu,†,‡,§ Ruizhong Zhang,†,‡,§ and Wei Chen*,†
1. Introduction
2. Synthesis of Functionalized Graphene and Graphene-Supported Electrocatalysts
2.1. Synthesis of Graphene and Heteroatom-Doped Graphene Electrocatalysts
2.1.1. Chemical Vapor Deposition (CVD)
2.1.2. Arc-Discharge Approach
2.1.3. Thermal Annealing Method
2.1.4. Plasma Treatment
2.1.5. Solvothermal and Hydrothermal Treatments
2.2. Graphene-Supported Pt and Low-Pt Nanocatalysts
2.2.1. Graphene-Supported Pt Nanocrystals (Pt/Graphene)
2.2.2. Graphene-Supported Low-Pt Alloy Nanocrystals
2.3. Graphene-Supported Non-Pt Nanocatalysts
2.3.1. Pd-Based Nanocatalysts/GNs
2.3.2. Au- and Ag-Based Nanocatalysts/GNs
2.3.3. Fe-Based Nanocatalysts/GNs
2.3.4. Co-Based Nanocatalysts/GNs
2.3.5. Ni-Based Nanocatalysts/GNs
2.3.6. Other Non-noble Nanocatalysts/GNs
2.4. Graphene-Supported Metal-Free Electrocatalysts
3. Structural Characterization and Properties of Graphene-Supported Nanoelectrocatalysts
3.1. Structural Characterization
3.1.1. Electron Microscopy (TEM, HRTEM, SEM, and STEM)
3.1.2. Scanning Probe Microscopy (AFM and STM)
3.1.3. Raman Spectroscopy
3.1.4. X-ray Photoelectron Spectroscopy (XPS)
3.1.5. X-ray Diffraction (XRD)
3.1.6. UV–Vis Spectroscopy
3.1.7. X-ray Absorption Near-Edge Structure (XANES)
3.1.8. Other Characterization Methods
3.2. Catalytic Properties
3.2.1. Intrinsic Catalytic Properties of Heteroatom-Doped Graphene
3.2.2. Catalytic Properties of Graphene-Supported Nanoelectrocatalysts
3.3. Other Unique Properties
4. Applications of Graphene-Supported Nanoelectrocatalysts
4.1. Electrooxidation of Small Organic Molecules at Anode of Fuel Cells
4.1.1. Methanol Oxidation Reaction (MOR)
4.1.2. Formic Acid Oxidation Reaction (FAOR)
4.1.3. Ethanol Oxidation Reaction (EOR)
4.1.4. Hydrogen Oxidation Reaction (HOR)
4.2. Oxygen Reduction Reaction (ORR) at Cathode
5. Conclusions and Future Outlook

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