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Amphiphilic Block Copolymers

By  Paschalis Alexandridis and Björn Lindman

Elsevier

2000

By
P. Alexandridis, Department of Chemical Engineering, State University of New York at Buffalo, NY 14260-4200, USA
B. Lindman, Center for Chemistry and Chemical Engineering, S-22100 Lund, Sweden

Description
It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.
The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.



Table of Contents

  Amphiphilic molecules: Small and large, Pages 1-12, Björn Lindman and Paschalis Alexandridis
  
  Modelling of the self-assembly of block copolymers in selective solvent, Pages 13-40, P. Linse

  On the origin of the solution behaviour of ethyleneoxide containing polymers, Pages 41-55, Gunnar Karlström
  
  Block copolymers of ethylene oxide and 1,2-butylene oxide, Pages 57-86, C. Booth, G.-E. Yu and V.M. Nace

  Self-Assembly of Block Polyelectrolytes, Pages 87-113, Lifeng Zhang, Karine Khougaz, Matthew Moffitt and Adi Eisenberg
  
  Formation of Amphiphilic Block Copolymer Micelles in Nonaqueous Solution,

  Structures of amphiphilic block copolymers in their liquid and solid states, , Anthony J. Ryan, Shao-Min Mai, J. Patrick, A. Fairclough and Ian W. Hamley

  Structural Polymorphism of Amphiphilic Block Copolymers in Mixtures with Water and Oil: Comparison with Solvent-Free Block Copolymers and Surfactant Systems, Pages 169-190, Paschalis Alexandridis, Ulf Olsson, Per Linse and Björn Lindman

  Small-Angle Scattering Studies of Block Copolymer Micelles, Micellar Mesophases and Networks, Pages 191-220, Kell Mortensen

  Fluorescence studies of amphiphilic block copolymers in solution, Pages 221-252, R. Zana

  Direct-Imaging Cryo-Transmission Electron Microscopy in the Study of Colloids and Polymer Solutions, Pages 253-280, Marganit Goldraich and Yeshayahu Talmon

Rheology Of Transient Networks Formed By The Association Of Hydrophobically Modified Water Soluble Polymers, Pages 281-304, Tom Annable, Richard Buscall and Rammile Ettelaie

  Applications of block copolymers, Pages 305-318, K. Holmberg

  Block copolymers in pharmaceutics, Pages 319-346, M. Malmsten


  Micelles of amphiphilic block copolymers as vehicles for drug delivery, Pages 347-376, Alexander V. Kabanov and Valery Yu. Alakhov

  Applications of Amphiphilic Copolymers in Separations, Pages 377-407, Mrten Svensson, Hans-Olof Johansson and Folke Tjerneld

  Polymeric Surfactants as Emulsion Stabilizers, Pages 409-422, R. Pons

[ Last edited by mengbaiyang on 2008-4-4 at 17:11 ]
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