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固体中的氢键--德国应用化学综述
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7楼2008-06-15 08:31:08
2楼2007-11-12 14:19:05
3楼2007-11-12 15:18:40
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多谢，这篇文章具体内容和链接见下： Review The Hydrogen Bond in the Solid State Thomas Steiner, Dr. * Institut für Chemie - Kristallographie Freie Universität Berlin Takustrasse 6, 14195 Berlin (Germany) Fax: (+49) 30-838-56702 email: Thomas Steiner (steiner@chemie.fu-berlin.de) *Correspondence to Thomas Steiner, Institut für Chemie - Kristallographie Freie Universität Berlin Takustrasse 6, 14195 Berlin (Germany) Fax: (+49) 30-838-56702 Keywords donor-acceptor systems; electrostatic interactions; hydrogen bonds; noncovalent interactions; proton transfer Abstract The hydrogen bond is the most important of all directional intermolecular interactions. It is operative in determining molecular conformation, molecular aggregation, and the function of a vast number of chemical systems ranging from inorganic to biological. Research into hydrogen bonds experienced a stagnant period in the 1980s, but re-opened around 1990, and has been in rapid development since then. In terms of modern concepts, the hydrogen bond is understood as a very broad phenomenon, and it is accepted that there are open borders to other effects. There are dozens of different types of X-HA hydrogen bonds that occur commonly in the condensed phases, and in addition there are innumerable less common ones. Dissociation energies span more than two orders of magnitude (about 0.2-40 kcal mol-1). Within this range, the nature of the interaction is not constant, but its electrostatic, covalent, and dispersion contributions vary in their relative weights. The hydrogen bond has broad transition regions that merge continuously with the covalent bond, the van der Waals interaction, the ionic interaction, and also the cation- interaction. All hydrogen bonds can be considered as incipient proton transfer reactions, and for strong hydrogen bonds, this reaction can be in a very advanced state. In this review, a coherent survey is given on all these matters. http://www3.interscience.wiley.c ... ETRY=1&SRETRY=0 |
9楼2008-06-23 19:10:55