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破军爱科研

木虫 (小有名气)

kg-mol,g-mol(国内常见)和lb-mol都是摩尔的单位,前面的质量单位只是表示这个摩尔数计算的标准,并不是真的表示分母一个kg,要不也应该是J/kg/mol或者J/kg·mol,是吧?
11楼2013-04-27 11:51:23
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破军爱科研

木虫 (小有名气)

kg-mol,g-mol(国内常见)和lb-mol都是摩尔的单位,前面的质量单位只是表示这个摩尔数计算的标准,并不是真的表示分母一个kg,要不也应该是J/kg/mol或者J/kg·mol,是吧?
12楼2013-04-27 11:51:56
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padian

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【答案】应助回帖

★ ★
安蓝2728: 金币+1, ★★★很有帮助 2013-05-15 11:14:07
sddtc888: 金币+1, 谢谢参与,欢迎常来! 2013-05-15 20:57:05
说下我个人观点

个人感觉好像kg-mol就表示千mol,也就是这个化学反应每发生1000 mol的焓变是多少kJ。

你可以算算看,对不对。

希望有帮助
13楼2013-04-29 10:49:56
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安蓝2728

新虫 (小有名气)

引用回帖:
10楼: Originally posted by 破军爱科研 at 2013-04-27 11:48:20
焓的单位不能带一个mol还带一个kg,可能的情况也就是kg标准的摩尔,区别于lb-mol和g-mol.你把kg-mol换算成g-mol试试,不行的话,就不知道为什么了

“Chemical engineers use the concept extensively, but the unit is rather small for industrial use.[15] For convenience in avoiding conversions, some American engineers adopted the pound-mole (noted lb-mol or lbmol), which is defined as the number of entities in 12 lb of 12C. One lb-mol is equal to 453.59237 mol.[16] In the metric system, chemical engineers once used the kilogram-mole (noted kg-mol), which is defined as the number of entities in 12 kg of 12C, and often referred to the mole as the gram-mole (noted g-mol), when dealing with laboratory data.[16] However modern chemical engineering practice is to use the kilomole (kmol), which is identical to the kilogram-mole, but whose name and symbol adopt the SI convention for standard multiples of metric units.”
这是我在维基百科里面找到的一段话,按照他这个理解的话Kg-mole(千克摩尔)似乎就是kmole(千摩尔),但是文献里基本没有这样转化的,这样转化出来都是错的!lb-mol (磅-摩尔)的转化是对的,1lb-mol =435.6mole
14楼2013-05-15 11:13:10
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安蓝2728

新虫 (小有名气)

引用回帖:
13楼: Originally posted by padian at 2013-04-29 10:49:56
说下我个人观点

个人感觉好像kg-mol就表示千mol,也就是这个化学反应每发生1000 mol的焓变是多少kJ。

你可以算算看,对不对。

希望有帮助

这样的转换在我看到的文献里不对,但是我在维基百科查到的是这样转换的!
15楼2013-05-15 11:15:05
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安蓝2728

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Apparently someone saw fit to undo the changes I made a few days ago to add a section to this article about other definitions of a mole (e.g., a kg-mol). He/she claimed that these changes were inappropriate as "These are not definitions of the mole." I must disagree: I have had numerous students confused by the use of kg-mol and lb-mol in textbooks, primarily because they too thought there was only one way to define a mole. Confusingly or otherwise, these definitions persist.

The term kg-mol is quite common among chemical engineers, and the lb-mol is even more common among chemical engineers from the USA. Software designed to assist in chemical plant design, such as PRO/II and ASPEN, all include these units. While these alternate definitions are rarely if ever seen outside the field of chemical engineering, their existence warrants at least being mentioned in an article dedicated to the definition of a mole.

Examples:

M. S. Peters, K. Timmerhaus, and R. E. West, Plant Design and Economics for Chemical Engineers, Fifth Edition. McGraw Hill (2002-2003). [Uses kg-mol, written as such.]
J. M. Douglas, Conceptual Design of Chemical Processes. Boston: McGraw Hill (1988). [Uses lb-mol, written as mol, throughout.]
Kaiserkarl13 (talk) 21:46, 20 January 2009 (UTC)

The pound-mole (also written without the hyphen) is a separate unit, although the link currently redirects here. The "kilogram-mole" is just an obsolescent name for the kilomole. Both of them are units of measurement of amount of substance that can be found in some US texts, but neither of them is the same unit as the mole. The confusion only arises if you pretend that they are. Physchim62 (talk) 22:12, 20 January 2009 (UTC)
The fact that pound-moles and kilogram-moles are separate units but are still called moles was my point! The fact that kilomoles and kilogram-moles are the same is a result of the fact that kilo(grams) and (kilograms) are the same, but the kg-mol is in no way an obsolete unit---it just happens to have the same meaning as a kmol and takes more characters to type. The purpose of the added text is to point out that there is more than one definition of a mole---with the standard SI unit of a mole being defined in terms of the gram. There's nothing pretend about it, though---the units kg-mol and lb-mol still occur, and they are no less valid as definitions of a mole. They just aren't the ones associated with the SI definition of "the mole." Kaiserkarl13 (talk) 23:00, 20 January 2009 (UTC)
You'd never say that pounds are another way of defining grams, so why do you say that the pound-mole is another way of defining the mole? It's another way of defining a unit of amount of substance, yes, but there is no law that says that all units of amount of substance have to be called "moles": in fact, there is a good pedagogical case for pointing out the exact opposite! Physchim62 (talk) 23:14, 20 January 2009 (UTC)
I'm not contending that the specific unit referred to as the mole (i.e., the SI unit defined as the number of entities in 12 g of 12-C) is the same unit as a kilogram-mole---obviously it isn't. The point of contention is that other units of amount of substance are invariably also called moles (with some modifier), perhaps merely due to lack of creativity. An excellent example is the unfortunate use of pounds in the English Imperial System to refer to both units of force and mass (these are, of course, different but related units). I think this point of contention could be settled by adding a section titled something like, "Units related to the mole" in which other units of amount of substance are defined. This would have the advantage of clarifying that "the mole" (unit) and "a mole" (generic term for amount of substance, usually but not always referring to the SI unit) can be different things. This would also solve the problem of pound-mole and kilogram-mole currently redirecting to Mole_(unit), which doesn't mention either of these other units. I may write these articles at a later date when I have the time. Kaiserkarl13 (talk) 21:35, 21 January 2009 (UTC)
Possibly this should be "Other units called mole" or something on those lines? That would make it clear that the lb-mole and kg-mole (both of which redirect here) are not actually the mole but rather something else with a confusingly similar name… I think I'll go add that. —Preceding unsigned comment added by Sabik (talk • contribs) 16:15, 27 January 2009 (UTC)
I have re-written the section, trying to be brief and non-contentious, while giving a source and giving the style of an encylopedia. I hope this helps. Chemical Engineer (talk) 17:52, 5 February 2009 (UTC)

把关于这个单位的讨论也贴上来,他们自己对这个单位似乎也很混乱!
16楼2013-05-15 11:17:54
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安蓝2728

新虫 (小有名气)

引用回帖:
11楼: Originally posted by 破军爱科研 at 2013-04-27 11:51:23
kg-mol,g-mol(国内常见)和lb-mol都是摩尔的单位,前面的质量单位只是表示这个摩尔数计算的标准,并不是真的表示分母一个kg,要不也应该是J/kg/mol或者J/kg·mol,是吧?

它们应该都是摩尔的单位
17楼2013-05-15 11:36:58
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