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zgm123456金虫 (小有名气)
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[求助]
求助,神呐,救救我吧
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小弟的一篇文章审稿意见回来了,文章小弟测了电化学,化合物里面有二价铜,在循环伏安曲线上在183MV处只有铜的氧化峰,没有还原峰(不可逆的峰),审稿人的意见是:in 2, the cupper is already at the oxidation number of II, so it is difficult to understand the presence of this wave. That would means, firstly the reduction at the electrode of the Cu(II) to Cu(I) and then the oxidation during the scan. But dispropotionation of Cu(I) can also occurs! Why author find irreversible wave ? Usually, such wave must be observed during the reduction of Cu(II) to Cu(I) follow by the disproportionnation to Cu(0) and Cu(II). 初学电化学测试,是在不明白怎么解释,导师又不管,求助各位大侠了,谢谢啊 |
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