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Chem. Soc. Rev.最新综述：软硬模板法合成多级孔道的宏观/介观材料
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最新一期的Chem. Soc. Rev.刊发了题为Controlling macro- and mesostructures with hierarchical porosity through combined hard and soft templating的综述，详细的介绍了结合软模板法和硬模板法合成具有多级孔道结构的宏观/介观材料的研究进展。文章18页，引文60篇。 Rigid, porous objects and surfactants serve as powerful templates for the formation of mesoporous and macroporous materials. When both types of template are combined in a single synthesis, materials with intricate architectures and hierarchical porosity can be obtained. In this tutorial review, we explain how to conduct syntheses with both soft and hard templates; moreover, we describe methods to control the final structure present in the templated material. Much of the foundation for multiple templating lies in the study of materials made with only one type of template. To establish a foundation in this area, a description of hard and soft templating is given, delving into the templates available and the steps required for effective templating. This leads into an extended discussion about materials templated with both hard and soft templates. Through the use of recent examples in the literature, we aim to show the diversity of structures possible through multiple templating and the advantages these structures can provide for a wide range of applications. An emphasis is placed on how various factors—such as the type of template, type of precursor, heat-treatment temperature, confinement within a small space, and template–template interactions—impact morphology. .  GA.gif [ 来自科研家族 材料家族 ] |
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2012-10-21 13:40:28, 5.11 M
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