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[资源] Chem. Rev. 最新综述：铂基双金属催化剂

在过去的几十年里，双金属催化剂，由于具有不同于其单金属组分的电子和化学性能，有望用于制备选择性好、活性高、稳定性强的催化剂，而受到广泛的研究。本文正是基于研究最多的铂基双金属催化剂，综述了双金属催化剂的合成、表征与应用。理论上密度泛函理论计算（DFT）和超高真空实验（VHU）已经取得了很大的进展。本文将会尝试把理论与实际结合起来。总之，本文内容翔实，实例丰富，是广大研究双金属的虫子们的福音！全文38页，引文423篇。

目录：
1. Introduction
1.1. Unique Properties of Bimetallic Surfaces and Catalysts
1.2. Scope of the Current Review
2. Preparation and Characterization of Bimetallic Surfaces and Catalysts
2.1. Model Surfaces
2.1.1. Preparation of Bimetallic Surfaces
2.1.2. Common Characterization Techniques for Bimetallic Surfaces
2.1.3. Example: Characterization of Ni/Pt Bimetallic Surfaces
2.2. Supported Catalysts
2.2.1. Synthesis of Supported Bimetallic Catalysts
2.2.2. Common Characterization Techniques for Bimetallic Catalysts
2.2.3. Example: Characterization of Supported Pt–Ni Bimetallic Catalysts
3. Stability of Pt-Based Bimetallic Surfaces with Different Adsorbates
3.1. DFT Calculations of Thermodynamic Stability
3.2. Experimental Verification of Surface Segregation
4. Utilization of Pt-Based Bimetallic Catalysts in Catalytic Reactions
4.1. Hydrogenation Reactions
4.1.1. C═C Hydrogenation
4.1.2. C═O Hydrogenation
4.1.3. N═O and C≡N Hydrogenation
4.2. Dehydrogenation Reactions
4.2.1. N–H Bond Scission
4.2.2. C–H Bond Scission
4.3. Reforming of Oxygenates
4.3.1. Reforming of Alcohols and Polyols
4.3.2. Reforming of Other Oxygenates
4.4. Other Important Catalytic Reactions
4.4.1. CO Oxidation
4.4.2. Water Gas Shift Reaction
4.4.3. CH4 Conversion
4.5. Brief Summary of Pt-Based Bimetallic Electrocatalysts
4.6. Brief Summary of Trimetallic Catalysts
5. Conclusions and Future Research Opportunities

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