|
|
【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★
Mally89: 金币+1, 感谢应助！~欢迎常来！~吼吼！~\(^o^)/~ 2012-03-30 22:46:40
被风掠过: 金币+2, 翻译EPI+1, ★有帮助, 翻译的有点不得体，不好意思了。 2012-03-31 12:07:32
sltmac: 金币+6 2012-04-03 21:35:31
非化学本行，浅尝翻译...
Structure of [Cd(Tipa)(L1)2] 3 H2O (1). Compound 1 contains one crystallographically unique CdII atom, two unique L1 anions, and one Tipa ligand (Figure 1a). The CdII atom is six-coordinated by three nitrogen atoms from three different Tipa ligands [Cd1N3 = 2.307(3), Cd1N6#1 = 2.306(3), and Cd1N7#2 =2.359(3) Å], and three oxygen atoms from two different L1
anions [Cd1O1 = 2.704(5), Cd1O2 = 2.260(2), and Cd1O3 = 2.253(2) Å] in a distorted octahedral geometry. The CdIIO and CdIIN distances are similar to the previously reported ones.10 The Tipa ligands in trimonodentate modes bridge adjacent CdII atoms to give an infinite 1D chain(Figure 1b). Two types of L1 anions are attached on both sidesof the chain.
[Cd(Tipa)(L1)2] 3 H2O (1)结构。化合物1包括1个结晶状的独特 CdII 原子，2个独特的 L1 阴离子和一个Tipa（三异丙醇胺?）配位（图1a）。 CdII原子是1个变形八面体几何结构的六配位，通过来自3个不同Tipa配位[Cd1N3 = 2.307(3), Cd1N6#1 = 2.306(3), and Cd1N7#2 =2.359(3) Å]的3个氮原子以及来自2个不同L1阴离子的3个氧原子而得到。CdIIO与CdII的间距相似于前面提到的间距。10（这个数字是什么？） 三重单配位模式桥结点CdII原子的Tipa配位， 给出一个无限的1D链（图1b）（个人认为原文这句话是不是缺少谓语，或者结合前面出现的数字‘10’是一个标题？）。两种类型的L1阴离子连附于链的双面。 |
|
回复此楼