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【答案】应助回帖
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缘分五月(金币+3): ★有帮助 2012-03-09 13:17:26
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我记得有个比较复杂的公式可以算的，里面需要知道结晶区的密度，无定形区的密度，自由能等等。你记得以下几篇文献里有公式：（1）Liang, Z.; Pan, P.; Zhu, B.; Inoue, Y.* Isomorphic Crystallization of Poly(hexamethylene adipate-co-butylene adipate): Regulating Crystal Modification of Polymorphic Polyester from Internal Crystalline Lattice. Macromolecules 2010, 43, 6429–6437. （2）Liang, Z.; Pan, P.; Zhu, B.; Inoue, Y.* Isomorphic Crystallization of Aliphatic Copolyesters Derived from 1,6-Hexanediol: Effect of the Chemical Structure of Comonomer Units on the Extent of Cocrystallization. Polymer 2011, 52, 2667-2676. （3）Liang, Z.; Pan, P.; Zhu, B.; Yang, J.; Inoue, Y.* Critical Role of the Conformation of Comonomer Units in Isomorphic Crystallization of Poly(hexamethylene adipate-co-butylene adipate) forming Poly(hexamethylene adipate) Type Crystal. Polymer 2011, 52, 5204-5211. |
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