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[×ÊÔ´] Progress in Nano-Electro-Optics VII: Chemical, Biological,

Progress in Nano-Electro-Optics VII: Chemical, Biological, and Nanophotonic Technologies for Nano-Optical Devices and Systems (Springer Series in Optical Sciences)
By Motoichi Ohtsu



•Publisher:   Springer
•Number Of Pages:   149
•Publication Date:   2010-01-01
•ISBN-10 / ASIN:   3642039502
•ISBN-13 / EAN:   9783642039508



Product Description:



This book focuses on chemical and nanophotonic technology to be used to develop novel nano-optical devices and systems. It begins with temperature- and photo-induced phase transition of ferromagnetic materials. Further topics include: energy transfer in artificial photosynthesis, homoepitaxial multiple quantum wells in ZnO, near-field photochemical etching and nanophotonic devices based on a nonadiabatic process and optical near-field energy transfer, respectively and polarization control in the optical near-field for optical information security. Taken as a whole, this overview will be a valuable resource for engineers and scientists working in the field of nano-electro-optics.

Contents



1 Photo-Induced Phase Transition in RbMnFe Prussian Blue
Analog-Based Magnet
H. Tokoro and S. Ohkoshi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Synthesis of Rubidium Manganese Hexacyanoferrate . . . . . . . . . . . . 2
1.3 Crystal Structure of Rubidium Manganese Hexacyanoferrate . . . . . 3
1.4 Temperature-Induced Phase Transition . . . . . . . . . . . . . . . . . . . . . . . . 5
1.4.1 Phase Transition Phenomenon in Magnetic Susceptibility . 5
1.4.2 Change in Electronic State . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.4.3 Structural Change . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.4.4 Mechanism. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.5 Ferromagnetism of the Low-Temperature Phase. . . . . . . . . . . . . . . . . 9
1.5.1 Magnetic Ordering and Heat Capacity . . . . . . . . . . . . . . . . . . 9
1.5.2 Entropy and Enthalpy of Magnetic Phase Transition . . . . . . 10
1.5.3 Long-Range Magnetic Ordering and Exchange Coupling . . . 12
1.5.4 Mechanism of Magnetic Ordering . . . . . . . . . . . . . . . . . . . . . . . 14
1.6 Control of Temperature-Induced Phase Transition . . . . . . . . . . . . . . 14
1.6.1 Huge Thermal Hysteresis Loop and a Hidden Stable Phase . 14
1.6.2 Thermodynamical Analysis of Thermal Hysteresis Loop . . . 16
1.7 Photo-Induced Phase Collapse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
1.7.1 Non Phase Transition Material . . . . . . . . . . . . . . . . . . . . . . . . . 18
1.7.2 Photo-Induced Structural Transition . . . . . . . . . . . . . . . . . . . . 19
1.7.3 Photo-Induced Phase Transition from a Metastable Phase to a Hidden Stable Phase . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
1.8 Photo-Induced Phase Transition at Room Temperature . . . . . . . . . . 21
1.9 Photomagnetism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
1.9.1 Photo-Induced Demagnetization by One-Shot-Laser-Pulse . 23
1.9.2 Reversible Photomagnetic Effect . . . . . . . . . . . . . . . . . . . . . . . . 25
1.10 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

2 Photoinduced Energy Transfer in Artificial Photosynthetic Systems
H. Imahori and T. Umeyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
2.2 Two-Dimensional Multiporphyrin Arrays . . . . . . . . . . . . . . . . . . . . . . 38
2.2.1 Self-assembled Monolayers of Porphyrins on Gold Electrodes 38
2.2.2 Self-assembled Monolayers of Porphyrins on ITO Electrodes 45
2.3 Three-Dimensional Porphyrin Arrays . . . . . . . . . . . . . . . . . . . . . . . . . . 47
2.3.1 Self-assembled Monolayers of Porphyrins on Metal Nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
2.3.2 Self-assembled Monolayers of Porphyrins on Semiconducting Nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . 56
2.4 Molecular Nanostructures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
2.4.1 Porphyrin J-Aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
2.4.2 Conjugated Polymer-Carbon Nanotube Composites . . . . . . . 62
2.5 Conclusions and Outlook . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

3 Electro-Magneto-Optics in Polarity-Controlled Quantum Structures on ZnO
H. Matsui and H. Tabata . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
3.2 Zn-Polarity and Quantum Structures . . . . . . . . . . . . . . . . . . . . . . . . . . 75
3.2.1 Surface Character . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
3.2.2 Homoepitaxial Growth and Optical Properties . . . . . . . . . . . . 77
3.2.3 MgxZn1-xO/ZnO Heteroepitaxy . . . . . . . . . . . . . . . . . . . . . . . . 79
3.2.4 Stranski-Krastanov Mode and Lateral Composition Modulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
3.2.5 Multiple Quantum Wells and Excitonic Recombination . . . . 84
3.3 Nonpolarity and Quantum Structures . . . . . . . . . . . . . . . . . . . . . . . . . 87
3.3.1 Nonpolar Growth of M-Face (10-10) . . . . . . . . . . . . . . . . . . . . 87
3.3.2 Step-Edge Barrier and Self-organized Nanowires . . . . . . . . . . 89
3.3.3 Linearly Polarized Light Emissions . . . . . . . . . . . . . . . . . . . . . . 92
3.3.4 Large Anisotropy of Electron Transport . . . . . . . . . . . . . . . . . 95
3.4 Quantum Well Geometry Based on ZnCoO . . . . . . . . . . . . . . . . . . . . 98
3.4.1 Spin and Band Engineering . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
3.4.2 Ferromagnetism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
3.4.3 Space Separation of Exciton and Localized Spin Systems . . . 105
3.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108

4 Nonadiabatic Near-Field Optical Polishing and Energy Transfers in Spherical Quantum Dots
W. Nomura, T. Yatsui, and M. Ohtsu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
4.2 Nanophotonic Polishing Using a Nonadiabatic Photochemical Reaction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
4.2.1 Nonadiabatic Optical Near-Field Etching . . . . . . . . . . . . . . . . 115
4.2.2 Experiment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
4.2.3 Results and Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116
4.3 Optical Near-Field Energy Transfer Between Spherical Quantum Dot Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
4.3.1 Exciton Energy Levels in Spherical Quantum Dots . . . . . . . . 118
4.3.2 Resonant Energy Transfer Between CdSe QDs . . . . . . . . . . . . 119
4.3.3 Control of the Energy Transfer Between ZnO QDs . . . . . . . . 125
4.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129

5 Shape-Engineered Nanostructures for Polarization Control in Optical Near- and Far-Fields
M. Naruse, T. Yatsui, T. Kawazoe, H. Hori, N. Tate, and M. Ohtsu . . . 131
5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
5.2 Polarization and Geometry on the Nanometer Scale . . . . . . . . . . . . . 132
5.3 Layout Dependence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
5.4 Symmetry in Polarization Conversion . . . . . . . . . . . . . . . . . . . . . . . . . 138
5.5 Hierarchy in Optical Near-Fields and Its Application to Multi-Layer Systems and Authentication Functions . . . . . . . . . . . . . 139
5.6 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147

[ À´×Ô¿ÆÑмÒ×å Сľ³æÇà´º¶¯Á¦ ]




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