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Progress in Nano-Electro-Optics VII: Chemical, Biological,
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Progress in Nano-Electro-Optics VII: Chemical, Biological, and Nanophotonic Technologies for Nano-Optical Devices and Systems (Springer Series in Optical Sciences) By Motoichi Ohtsu •Publisher: Springer •Number Of Pages: 149 •Publication Date: 2010-01-01 •ISBN-10 / ASIN: 3642039502 •ISBN-13 / EAN: 9783642039508 Product Description: This book focuses on chemical and nanophotonic technology to be used to develop novel nano-optical devices and systems. It begins with temperature- and photo-induced phase transition of ferromagnetic materials. Further topics include: energy transfer in artificial photosynthesis, homoepitaxial multiple quantum wells in ZnO, near-field photochemical etching and nanophotonic devices based on a nonadiabatic process and optical near-field energy transfer, respectively and polarization control in the optical near-field for optical information security. Taken as a whole, this overview will be a valuable resource for engineers and scientists working in the field of nano-electro-optics. Contents 1 Photo-Induced Phase Transition in RbMnFe Prussian Blue Analog-Based Magnet H. Tokoro and S. Ohkoshi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Synthesis of Rubidium Manganese Hexacyanoferrate . . . . . . . . . . . . 2 1.3 Crystal Structure of Rubidium Manganese Hexacyanoferrate . . . . . 3 1.4 Temperature-Induced Phase Transition . . . . . . . . . . . . . . . . . . . . . . . . 5 1.4.1 Phase Transition Phenomenon in Magnetic Susceptibility . 5 1.4.2 Change in Electronic State . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.4.3 Structural Change . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 1.4.4 Mechanism. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 1.5 Ferromagnetism of the Low-Temperature Phase. . . . . . . . . . . . . . . . . 9 1.5.1 Magnetic Ordering and Heat Capacity . . . . . . . . . . . . . . . . . . 9 1.5.2 Entropy and Enthalpy of Magnetic Phase Transition . . . . . . 10 1.5.3 Long-Range Magnetic Ordering and Exchange Coupling . . . 12 1.5.4 Mechanism of Magnetic Ordering . . . . . . . . . . . . . . . . . . . . . . . 14 1.6 Control of Temperature-Induced Phase Transition . . . . . . . . . . . . . . 14 1.6.1 Huge Thermal Hysteresis Loop and a Hidden Stable Phase . 14 1.6.2 Thermodynamical Analysis of Thermal Hysteresis Loop . . . 16 1.7 Photo-Induced Phase Collapse . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 1.7.1 Non Phase Transition Material . . . . . . . . . . . . . . . . . . . . . . . . . 18 1.7.2 Photo-Induced Structural Transition . . . . . . . . . . . . . . . . . . . . 19 1.7.3 Photo-Induced Phase Transition from a Metastable Phase to a Hidden Stable Phase . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 1.8 Photo-Induced Phase Transition at Room Temperature . . . . . . . . . . 21 1.9 Photomagnetism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 1.9.1 Photo-Induced Demagnetization by One-Shot-Laser-Pulse . 23 1.9.2 Reversible Photomagnetic Effect . . . . . . . . . . . . . . . . . . . . . . . . 25 1.10 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 2 Photoinduced Energy Transfer in Artificial Photosynthetic Systems H. Imahori and T. Umeyama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 2.2 Two-Dimensional Multiporphyrin Arrays . . . . . . . . . . . . . . . . . . . . . . 38 2.2.1 Self-assembled Monolayers of Porphyrins on Gold Electrodes 38 2.2.2 Self-assembled Monolayers of Porphyrins on ITO Electrodes 45 2.3 Three-Dimensional Porphyrin Arrays . . . . . . . . . . . . . . . . . . . . . . . . . . 47 2.3.1 Self-assembled Monolayers of Porphyrins on Metal Nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 2.3.2 Self-assembled Monolayers of Porphyrins on Semiconducting Nanoparticles . . . . . . . . . . . . . . . . . . . . . . . . . . 56 2.4 Molecular Nanostructures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 2.4.1 Porphyrin J-Aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 2.4.2 Conjugated Polymer-Carbon Nanotube Composites . . . . . . . 62 2.5 Conclusions and Outlook . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 3 Electro-Magneto-Optics in Polarity-Controlled Quantum Structures on ZnO H. Matsui and H. Tabata . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 3.2 Zn-Polarity and Quantum Structures . . . . . . . . . . . . . . . . . . . . . . . . . . 75 3.2.1 Surface Character . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 3.2.2 Homoepitaxial Growth and Optical Properties . . . . . . . . . . . . 77 3.2.3 MgxZn1-xO/ZnO Heteroepitaxy . . . . . . . . . . . . . . . . . . . . . . . . 79 3.2.4 Stranski-Krastanov Mode and Lateral Composition Modulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 3.2.5 Multiple Quantum Wells and Excitonic Recombination . . . . 84 3.3 Nonpolarity and Quantum Structures . . . . . . . . . . . . . . . . . . . . . . . . . 87 3.3.1 Nonpolar Growth of M-Face (10-10) . . . . . . . . . . . . . . . . . . . . 87 3.3.2 Step-Edge Barrier and Self-organized Nanowires . . . . . . . . . . 89 3.3.3 Linearly Polarized Light Emissions . . . . . . . . . . . . . . . . . . . . . . 92 3.3.4 Large Anisotropy of Electron Transport . . . . . . . . . . . . . . . . . 95 3.4 Quantum Well Geometry Based on ZnCoO . . . . . . . . . . . . . . . . . . . . 98 3.4.1 Spin and Band Engineering . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 3.4.2 Ferromagnetism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 3.4.3 Space Separation of Exciton and Localized Spin Systems . . . 105 3.5 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 4 Nonadiabatic Near-Field Optical Polishing and Energy Transfers in Spherical Quantum Dots W. Nomura, T. Yatsui, and M. Ohtsu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 4.2 Nanophotonic Polishing Using a Nonadiabatic Photochemical Reaction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 4.2.1 Nonadiabatic Optical Near-Field Etching . . . . . . . . . . . . . . . . 115 4.2.2 Experiment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 4.2.3 Results and Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 4.3 Optical Near-Field Energy Transfer Between Spherical Quantum Dot Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 4.3.1 Exciton Energy Levels in Spherical Quantum Dots . . . . . . . . 118 4.3.2 Resonant Energy Transfer Between CdSe QDs . . . . . . . . . . . . 119 4.3.3 Control of the Energy Transfer Between ZnO QDs . . . . . . . . 125 4.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129 5 Shape-Engineered Nanostructures for Polarization Control in Optical Near- and Far-Fields M. Naruse, T. Yatsui, T. Kawazoe, H. Hori, N. Tate, and M. Ohtsu . . . 131 5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 5.2 Polarization and Geometry on the Nanometer Scale . . . . . . . . . . . . . 132 5.3 Layout Dependence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 5.4 Symmetry in Polarization Conversion . . . . . . . . . . . . . . . . . . . . . . . . . 138 5.5 Hierarchy in Optical Near-Fields and Its Application to Multi-Layer Systems and Authentication Functions . . . . . . . . . . . . . 139 5.6 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 [ À´×Ô¿ÆÑмÒ×å Сľ³æÇà´º¶¯Á¦ ] [ Last edited by wenke1526 on 2011-12-19 at 11:05 ] |
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