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1Â¥: Originally posted by beefly at 2011-09-10 04:18:24:
http://pubs.acs.org/doi/abs/10.1021/jp2057404

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pi_g * pi_u £½ (sigma_u^+) * (sigma_u^£­) * (delta_u)

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ÒÔ2S(infinit) ΪÀý£º
pi_g µÄ¼£Îª £­2cosA
pi_uµÄ¼£Îª 2cosA
pi_g * pi_u = -4cosA^2 = -2cos(2A) - 2

sigma_u^+/-µÄ¼£Îª-1£¬ sigma_g^-µÄ¼£Îª+1, delta_uµÄ¼£Îª£­2cos(2A)
(sigma_u^+) * (sigma_u^-) * (delta_u) = - 1 - 1 -2cos(2A) = pi_g * pi_u

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