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Carena

铁杆木虫 (知名作家)

【答案】应助回帖

两种结构的HOMO和LUMO能级是不一样的,会对载流子的注入产生影响,发光颜色也是不一样的。其它关于Alq3的研究则主要集中在光电器件的效率和稳定性上。2008年,Yuki Nagata 也模拟了amorphous Alq3载流子传输过程的研究表明其传输是一种跳跃机制,和电场与温度的关系是Poole-Frenkel机制,同年,J. J. Kwiatkowski 用Monte Carlo 模拟了amorphous Alq3,结果表明电子的迁移率为空穴的two orders ,但是他计算的迁移率与电场的关系不符合Poole-Frenkel机制,还有一些从理论上探讨对Alq3的配体进行不同取代对其光物理性质的影响的报道。在理论上对Alq3的传输特性的研究大多仅限于经式薄膜和β-晶相,还有一些结合态密度概念从定性的角度探讨其传输电子的高效性,以上这些研究都大多仅限于晶体。

The energy level of HOMO and LUMO of the two structures is not the same, which would influence the injection of the carrier, and their light color is not the same, either. Other studies on Alq3 mainly focused the efficiency and the stability of the photoelectric devices. In 2008, Yuki Nagata also simulated the transmission of amorphous Alq3 carrier which indicated that its transmission was a leaping mechanism, and its relation with electric field and temperature was Poole-Frenkel mechanism. In the same year, JJ Kwiatkowski used Monte Carlo to make an simulation of amorphous Alq3, which showed that the mobility of electron was two orders of the hole, but he found that the relation between the mobility and the electric field did not match the Poole-Frenkel mechanism. There were also reports which discussed theoretically the influence of the different substitution of the ligands of Alq3 on its photophysical properties. The theoretical study of the transmission characteristics of Alq3 are mainly restricted in the film andβ-crystalline phase. Besides, there are some other reserches which focus on the efficiency of transmit electrons combined with the state density from the qualitative point of view. Nevertheless, all the studies mentioned above are mostly limited to the crystal.
Impossible Is Nothing
11楼2011-07-26 12:18:21
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Carena

铁杆木虫 (知名作家)

【答案】应助回帖

zhang727626(金币+100, 翻译EPI+1): 2011-07-30 15:04:41
基于如上所述,我们用MD得到了alq3的amorphous material,并对其载流子迁移率进行理论表征,探讨分子构型和固体堆积对其传输性能的影响,以求对Alq3的理解更加完善。对载流子传输的扩散系数编程进行蒙特卡罗模拟,进而使所有结果都建立在计算的基础上,从而对实验进行更加深入指导

Taken together, we used MD and got the amorphous material of Alq3. we made a theoretic representation of the mobility of its carrier and also discussed the influence of molecular structure and solid accumulation on its transmission performance in order to get a more complete understanding of Alq3. Moreover, we made a Monte Carlo simulation of the diffusion coefficient programming of the carrier transmission, from which we could get all the results at the basis of calculation for further guide to the experiment.
Impossible Is Nothing
12楼2011-07-26 12:29:54
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zhang727626

新虫 (小有名气)

引用回帖:
12楼: Originally posted by Carena at 2011-07-26 12:29:54:
基于如上所述,我们用MD得到了alq3的amorphous material,并对其载流子迁移率进行理论表征,探讨分子构型和固体堆积对其传输性能的影响,以求对Alq3的理解更加完善。对载流子传输的扩散系数编程进行蒙特卡罗模拟, ...

你好,https://muchong.com/bbs/viewthread.php?tid=3572326
麻烦你帮我翻译一下,非常感谢
13楼2011-09-08 17:05:14
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