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Chem Soc Rev最新： 天然大分子荧光效应
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From being a niche area only a few decades ago, fluorous chemistry has gained momentumand is, nowadays, a fervent area of research. It has brought forth, in fact, numerous applicativeinnovations that stretch among different fields: from catalysis to separation science, fromsupramolecular to materials and analytical chemistry. Recently, the unique features ofperfluorinated compounds have reached the attention of the biochemists’ audience. Thistutorial review introduces the basic concepts of fluorous chemistry and illustrates its mainbiomolecular applications. Special attention has been given to fluorous microarrays and their combination with Mass-Spectroscopy (MS) techniques, to protein properties modification by the introduction of local fluorous domains, and to the most recent applications of 19F-Magnetic Resonance Imaging (19F-MRI). |
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