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li1cai2fu3
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li1cai2fu3
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yutian1224
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Journal of Inorganic and Nuclear Chemistry Volume 25, Issue 11, November 1963, Pages 1389-1393 -------------------------------------------------------------------------------- doi:10.1016/0022-1902(63)80408-X | How to Cite or Link Using DOI Copyright © 1963 Published by Elsevier Science Ltd. Permissions & Reprints The infra-red spectra of metal(II)-hydrazine complexes This article is not included in your organization's subscription. However, you may be able to access this article under your organization's agreement with Elsevier. L. Sacconi and A. Sabatini Istituto di Chimica Generale e Inorganica della Universita di Firenze, Via Jacopo Nardi 39, Firenze, Italy Received 28 February 1963; revised 1 May 1963. Available online 16 May 2003. Abstract The infra-red spectra of some hydrazine-metal complexes of the general formula M(N2H4)2Cl2 have been measured in the 2–35 μ region. A comparison of the spectra of Cd(N2H4)2Cl2 and Cd(N2D4)2Cl2 enables the assignment of the observed absorption bands. The sequence of some of the molecular modes of vibration (such as the NH2 twisting, rocking, torsion and the N---N and M---N stretching frequencies) agrees closely with the natural order of the stability of bivalent complexes. |
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