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rchen

铜虫 (正式写手)

[交流] 【讨论】这个审稿意见应该怎样处理。

文章有消息了,编辑给了个大修,有个审稿意见我不知怎样处理,怎样回答提问。谢谢各位
1 As with compounds 1 and 2, from the large sizes of the Ueq and Uii values for
the unit-occupancy water oxygens O5, O6 and O7 it would seem likely that these
water molecules may be only present with partial occupancy and should have
their occupancy parameters refined as free variables.
2 The water oxygen O7 has been assigned 0.5 occupancy but from the large
sizes of the Ueq and Uii values for this half-occupancy water O7 atom it would
seem likely that it may be only present with a much smaller partial occupancy.
and should have the partial-occupancy parameter refined as a free variable.
3 We see from the CIF that 30 restraints were used in the refinement.
We should be told - at least in the "_refine_special_details" section of
the CIF or in the ESI text - exactly what these restraints were and why
they were necessary.
4  Note also that the space group Pnma chosen by the authors is not uniquely
determined by the systematoc absences which also allow space group to be an
alternative setting of Pna2~1~ with no crystallographically imposed symmetry.
Was structure solution and refinement in this space group considered??
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rchen

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引用回帖:
Originally posted by jiangqibai at 2010-09-03 16:55:26:
O7的占有率小于0。5
cif表中要告诉使用限制命令的细节及原因
你的空间群最好用Platoni检测合适的空间群 有可能有错误!

谢谢你,我用Platon 检查空间群没什么问题,之前是 Pna2~1~ 后来精修转成pnma了,这个现在怎么处理
6楼2010-09-03 20:27:13
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jiangqibai

木虫 (正式写手)

要求你的O5、O6、O7无序处理!

★ ★ ★
帝夫(金币+3):谢谢回帖交流~ 2010-09-03 19:07:10
rchen(金币+5): 2010-09-03 20:21:45
O7的占有率小于0。5
cif表中要告诉使用限制命令的细节及原因
你的空间群最好用Platoni检测合适的空间群 有可能有错误!
2楼2010-09-03 16:55:26
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huahua1216

至尊木虫 (文坛精英)


帝夫(金币+1):谢谢回帖交流~ 2010-09-03 19:07:36
rchen(金币+5): 2010-09-03 20:21:57
和楼上差不多 只是说你的水分子是不是占有率小于0.5 可以考虑TG测定水的具体含量
3楼2010-09-03 17:03:19
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Nocturne

木虫 (正式写手)

rchen(金币+5): 2010-09-03 20:22:12
wsht212:谢谢交流,希望常来! 2010-09-04 13:28:41
估计空间群什么的有问题,最好用Platon检查下,然后再回复编辑的问题时表现的谦逊点,一条一条的回答
4楼2010-09-03 17:38:48
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