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[资源] 【经典教材】Seymour/Carraher's Polymer Chemistry (第七版) 聚合物化学

Seymour/Carraher's Polymer Chemistry, Seventh Edition
Author: Charles E. Carraher Jr.
Format: PDF；File Size: 11.8MB；Page: 729
Publisher: CRC Press, 2008
ISBN-10: 1-4200-5102-4
ISBN-13: 978-1-4200-5102-5

Contents
Chapter 1 Introduction to Polymers 1
Chapter 2 Polymer Structure (Morphology) 19
Chapter 3 Molecular Weight of Polymers 49
Chapter 4 Polycondensation Polymers (Step-Reaction Polymerization) 83
Chapter 5 Ionic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization) 135
Chapter 6 Free Radical Chain Polymerizatio n (Addition Polymerization) 173
Chapter 7 Copolymerization 207
Chapter 8 Composites and Fillers 237
Chapter 9 Naturally Occurring Polymers: Plants 259
Chapter 10 Naturally Occurring Polymers: Animals 301
Chapter 11 Organometallic and Inorganic–Organic Polymers 361
Chapter 12 Inorganic Polymers 383
Chapter 13 Testing and Spectrometric Characterization of Polymers 425
Chapter 14 Rheology and Physical Tests 459
Chapter 15 Additives 483
Chapter 16 Reactions on Polymers 497
Chapter 17 Synthesis of Reactants and Intermediates for Polymers 525
Chapter 18 Polymer Technology 545
Chapter 19 Selected Topics 583
Solutions 625
Appendices 653[ Last edited by 中山羊 on 2012-3-6 at 09:02 ]
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Table of Contents
Chapter 1 Introduction to Polymers 1
1.1 History of Polymers 1
1.2 Why Polymers? 8
1.3 Today’s Market place 12
1.4 Summary 16
Glossary 17
Exercises 17
Further Reading 17
General Encyclopedias and Dictionaries 18
Chapter 2 Polymer Structure (Morphology) 19
2.1 Stereochemistry of Polymers 20
2.2 Molecular Interactions 27
2.3 Polymer Crystals 34
2.4 Amorphous Bulk State 38
2.5 Polymer Structure–Property Relationships 38
2.6 Cross-Linking 41
2.7 Crystalline and Amorphous Combinations 42
2.8 Summary 45
Glossary 46
Exercises 47
Additional Reading 48
Chapter 3 Molecular Weight of Polymers 49
3.1 Introduction 49
3.2 Solubility 51
3.3 Average Molecular Weight Values 53
3.4 Fractionation of Polydisperse Systems 59
3.5 Chromatography 59
3.6 Colligative Molecular Weights 62
3.7 Light-Scattering Photometry 64
3.8 Other Techniques  70
3.9 Viscometry 72
3.10 Summary 78
Glossary 79
Exercises 80
Further Reading 82
Chapter 4 Polycondensation Polymers (Step-Reaction Polymerization) 83
4.1 Comparison between Polymer Type and Kinetics of Polymerization 83
4.2 Introduction 88
4.3 Stepwise Kinetics 88
4.4 Polycondensation Mechanisms 92
4.5 Polyesters 94
4.6 Polycarbonates 100
4.7 Synthetic Polyamides 103
4.8 Polyimides 109
4.9 Polybenzimidazoles and Related Polymers 110
4.10 Polyurethanes and Polyureas 110
4.11 Polysulfides 113
4.12 Polyethers and Epoxys 114
4.13 Polysulfones 117
4.14 Poly(ether ketone) and Polyketones 119
4.15 Phenolic and Amino Plastics 120
4.16 Furan Resins 122
4.17 Synthetic Routes 122
4.18 Liquid Crystals 123
4.19 Microfibers 127
4.20 General Stepwise Polymerization 128
4.21 Summary 130
Glossary 131
Exercises 133
Further Reading 134
Chapter 5 Ionic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization) 135
5.1 Chain-Growth Polymerization—General 136
5.2 Cationic Polymerization 137
5.3 Anionic Polymerization 143
5.4 Stereoregularity and Stereogeometry 148
5.5 Polymerization with Complex Coordination Catalysts 148
5.6 Soluble Stereoregulating Catalysis 150
5.7 Polyethylenes 153
5.8 Polypropylene 158
5.9 Polymers from 1,4-Dienes 162
5.10 Polyisobutylene 164
5.11 Metathesis Reactions 165
5.12 Zwitterionic Polymerization 165
5.13 Isomerization Polymerization 166
5.14 Precipitation Polymerization 167
5.15 Summary 167
Glossary 168
Exercises 169
Further Reading 170
Chapter 6 Free Radical Chain Polymerization (Addition Polymerization) 173
6.1 Initiators for Free Radical Chain Polymerization 173
6.2 Mechanism for Free Radical Chain Polymerization 177
6.3 Chain Transfer 183
6.4 Polymerization Techniques 185
6.5 Fluorine-Containing Polymers 190
6.6 Polystyrene 193
6.7 Poly(vinyl chloride) 194
6.8 Poly(methyl methacrylate) 187
6.9 Poly(vinyl alcohol) and Poly(vinyl acetals) 199
6.10 Poly(acrylonitrile) 200
6.11 Solid State Irradiation Polymerization 201
6.12 Plasma Polymerizations 202
6.13 Summary 203
Glossary 203
Exercises 204
Further Reading 205
Chapter 7 Copolymerization 207
7.1 Kinetics of Copolymerization 208
7.2 The Q–e Scheme 212
7.3 Commercial Copolymers 213
7.4 Block Copolymers 214
7.5 Graft Copolymers 216
7.6 Elastomers 216
7.7 Thermoplastic Elastomers 218
7.8 Blends 221
7.9 Networks—General 224
7.10 Polymer Mixtures 225
7.11 Dendrites 226
7.12 Ionomers 228
7.13 Viscosity Modifiers 229
7.14 Summary 233
Glossary 234
Exercises 235
Further Reading 236
Chapter 8 Composites and Fillers 237
8.1 Fillers 237
8.2 Types of Composites 238
8.3 Long Fiber Composites—Theory 240
8.4 Fibers and Resins 242
8.5 Long Fiber Composites—Applications 244
8.6 Nanocomposites 248
8.7 Fabrication 251
8.8 Metal–Matrix Composites 253
8.9 Summary 256
Glossary 256
Exercises 257
Further Reading 257
Chapter 9 Naturally Occurring Polymers: Plants 259
9.1 Polysaccharides 260
9.2 Cellulose 261
9.3 Cellulose-Regenerating Processes 265
9.4 Esters and Ethers of Cellulose 268
9.5 Starch 272
9.6 Homopolysaccharides 275
9.7 Heteropolys accharides 279
9.8 Synthetic Rubbers 283
9.9 Naturally Occurring Polyisoprenes 289
9.10 Resins 291
9.11 Balloons 292
9.12 Lignin 293
9.13 Melanins 295
9.14 Summary 296
Glossary 297
Exercises 298
Further Reading 299
Chapter 10 Naturally Occurring Polymers: Animals 301
10.1 Proteins 302
10.2 Levels of Protein Structure 305
10.3 Nucleic Acids 316
10.4 Flow of Biological Information 321
10.5 RNA Interference 323
10.6 Polymer Structure 325
10.7 Protein Folding 328
10.8 Genetic Engineering 330
10.9 DNA Profiling 333
10.10 The Human Genome: General 335
10.11 Chromosomes 341
10.12 Proteomics 352
10.13 Protein Site Activity Identification 354
10.14 Summary 354
Glossary 355
Exercises 358
Further Reading 358
Chapter 11 Organometallic and Inorganic–Organic Polymers 361
11.1 Introduction 361
11.2 Inorganic Reaction Mechanisms 362
11.3 Condensation Organometallic Polymers 364
11.4 Coordination Polymers 370
11.5 Addition Polymers 373
11.6 Ion-Exchange Resins 378
11.7 Summary 380
Glossary 380
Exercises 380
Further Reading 381
Chapter 12 Inorganic Polymers 383
12.1 Introduction 383
12.2 Portland Cement 383
12.3 Other Cements 386
12.4 Silicates 386
12.5 Silicon Dioxide (Amorphous) 390
12.6 Kinds of Amorphous Glass 393
12.7 Safety Glass 394
12.8 Lenses 396
12.9 Sol–Gel 398
12.10 Silicon Dioxide (Crystalline Forms) —Quartz Forms 401
12.11 Silicon Dioxide in Electronic Chips 403
12.12 Silicon Dioxide in Optical Fibers 403
12.13 Asbestos 404
12.14 Polymeric Carbon—Diamond 405
12.15 Polymeric Carbon —Graphite 405
12.16 Internal Cyclization—Carbon Fibers and Related Materials 407
12.17 Carbon Nanotubes 408
12.18 Bitumens 414
12.19 Carbon Black 415
12.20 Polysulfur 417
12.21 Ceramics 417
12.22 High-Temperature Superconductors 419
12.23 Zeolites 420
12.24 Summary 421
Glossary 422
Exercises 423
Further Reading 424
Chapter 13 Testing and Spectrometric Characterization of Polymers 425
13.1 Spectronic Characterization of Polymers 426
13.2 Surface Characterization 430
13.3 Amorphous Region Determinations 436
13.4 Mass Spectrometry 436
13.5 Thermal Analysis 437
13.6 Thermal Property Tests 439
13.7 Flammability 442
13.8 Electrical Properties: Theory 443
13.9 Electric Measurements 445
13.10 Optical Properties Tests 448
13.11 Weatherability 450
13.12 Chemical Resistance 450
13.13 Measurement of Particle Size 451
13.14 Measurement of Adhesion 452
13.15 Permeability and Diffusion 453
13.16 Summary 455
Glossary 456
Exercises 456
Further Reading 457
Chapter 14 Rheology and Physical Tests 459
14.1 Rheology 459
14.2 Typical Stress–Strain Behavior 465
14.3 Stress–Strain Relationships 469
14.4 Specific Physical Tests 471
14.5 Summary 479
Glossary 479
Exercises 480
Further Reading 481
Chapter 15 Additives 483
15.1 Plasticizers 484
15.2 Antioxidants 487
15.3 Heat Stabilizers 489
15.4 Ultraviolet Stabilizers 489
15.5 Flame Retardants 490
15.6 Colorants 491
15.7 Curing Agents 491
15.8 Antistatic Agents—Antistats 492
15.9 Chemical Blowing Agents 492
15.10 Compatibilizers 492
15.11 Impact Modifiers 492
15.12 Processing Aids 492
15.13 Lubricants 493
15.14 Microorganism Inhibitors 493
15.15 Summary 493
Glossary 494
Exercises 495
Further Reading 495
Chapter 16 Reactions on Polymers 497
16.1 Reactions with Polyolefines and Polyenes 497
16.2 Reactions of Aromatic and Aliphatic Pendant Groups 498
16.3 Degradation 499
16.4 Cross-Linking 501
16.5 Reactivities of End Groups 503
16.6 Supramolecules and Self-Assembly 504
16.7 Transfer and Retention of Oxygen 511
16.8 Nature’s Macromolecular Catalysts 515
16.9 Mechanisms of Energy Absorption 519
16.10 Breakage of Polymeric Materials 521
16.11 Summary 523
Glossary 523
Exercises 524
Further Reading 524
Chapter 17 Synthesis of Reactants and Intermediates for Polymers 525
17.1 Monomer Synthesis from Basic Feedstocks 525
17.2 Reactants for Step-Reaction Polymerization 530
17.3 Synthesis of Vinyl Monomers 536
17.4 Synthesis of Free Radical Initiators 540
17.5 Summary 542
Glossary 542
Exercises 543
Further Reading 543
Chapter 18 Polymer Technology 545
18.1 Fibers 549
18.2 Elastomers 554
18.3 Films and Sheets 557
18.4 Polymeric Foams 559
18.5 Reinforced Plastics (Composites) and Laminates 559
18.6 Molding 562
18.7 Casting 571
18.8 Extrusion 571
18.9 Coatings 572
18.10 Adhesives 575
18.11 Summary 578
Glossary 578
Exercises 580
Further Reading 581
Chapter 19 Selected Topics 583
19.1 Conductive Polymeric Materials 583
19.2 Nonlinear Optical Behavior 591
19.3 Photophysics 591
19.4 Drug Design and Activity 593
19.5 Synthetic Biomedical Polymers 595
19.6 Sutures 601
19.7 Geotextiles 606
19.8 Smart Materials 607
19.9 High-Performance Thermoplastics 608
19.10 Construction and Building 610
19.11 Flame-Resistant Textiles 612
19.12 Water-Soluble Polymers 614
19.13 Anaerobic Adhesives 615
19.14 Hydrogels 617
19.15 Emerging Polymers 617
19.16 Summary 620
Glossary 621
Exercises 622
Further Reading 622
Solutions 625
Appendices 653
A. Symbols 653
B. Trade Names 657
C. Syllabus 689
D. Polymer Core Course Com mittees 691
E. Structures of Common Polymers 693
F. Mathematical Values and Units 697
G. Comments on Health 699
H. ISO 9000 and 14000 701
I. Electronic Education Web Sites 703
J. Stereogeometry of Polymers 705
K. Statistical Treatment of Measurements 713
L. Combinatorial Chemistry 715
M. Polymerization Reactors 717
N. Material Selection Charts 721

[ Last edited by 中山羊 on 2012-3-6 at 16:26 ]
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