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导师沈晓,现任武汉大学高等研究院教授,博士生导师,为海外高层次人才计划青年项目入选者,科技部重点研发计划青年项目首席科学家,武汉大学“弘毅青年学者”特聘教授。实验室近三年发表影响因子10分以上的一区论文10余篇,多名学生获得学校及国家奖学金。实验室主页:http://xiaoshen.whu.edu.cn/
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课题组近几年代表性论文:
1. z. li, y. zhang, y. zhang, x. he, x. shen*. “diastereoselective synthesis of monofluorocyclohexenes through photocatalyzed cascade cyclization of gem-difluoroalkenes and α,β-unsaturated carbonyl compounds” angew. chem. int. ed. 2023, 62, e202303218.
2. g. zhou#, z. guo#, x. shen*. "electron-rich oxycarbenes: new synthetic and catalytic applications beyond group 6 fischer carbene complexes" angew. chem. int. ed. 2023, 62, e202217189. (# contributed equally).
3. y. zhang#, y. zhang#, c. ye, x. qi*, l.-z. wu*, x. shen*. ''cascade cyclization of alkene-tethered acylsilanes and allylic sulfones enabled by unproductive energy transfer photocatalysis'' nat. commun. 2022, 13, 6111. (# contributed equally).
4. s. chen, x. he, c. jin, w. zhang, y. yang, s. liu, y. lan*, k. n. houk*, x. shen*. "nickel-catalyzed cross-redistribution between hydrosilanes and silacyclobutanes" angew. chem. int. ed. 2022, 61, e202213431.
5. y. zhang#, y. niu#, y. guo, j. wang, y. zhang, s. liu, x. shen*. "photocatalyzed cascade reactions of cyclopropanols and α-trifluoromethyl-substituted olefins for the synthesis of fused gem-difluorooxetanes" angew. chem. int. ed. 2022, 61, e202212201. (# contributed equally).
6. z. zhu, w. zhang, y. zhang, s. liu, x. shen*. ''visible-light-induced [4+1] cyclization-aromatization of acylsilanes and ɑ, β-unsaturated ketones'' ccs chem. 2022, doi: 10.31635/ccschem.022.202202199.
7. s. chen, x. he, y. jin, y. lan*, x. shen*. ''copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (e)-allylsilanes'' nat. commun. 2022, 13 (1): 3691.
8. y. zhang#, g. zhou#, x. gong#, z. guo, x. qi*, x. shen*. ''diastereoselective transfer of tri(di)fluoroacetylsilanes-derived carbenes to alkenes'' angew. chem. int. ed. 2022, 61, e202202175. (# contributed equally).
9. g. zhou, x. shen*. ''synthesis of cyclopropenols enabled by visible-light-induced organocatalyzed [2+1] cyclization'' angew. chem. int. ed. 2022, 61, e202115334. (highlighted by synfacts)
10. z. yang#,y. niu#,x. he, s. chen, s. liu, z. li, x. chen, y. zhang, y. lan*, x. shen*. ''tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer'' nat. commun. 2021, 12, 2131. (# contributed equally).
11. x. chen#, x. gong#, z. li, g. zhou, z. zhu, w. zhang, s. liu, x. shen*. "direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents" nat. commun. 2020, 11, 2756. (# contributed equally; highlighted by synfacts). |