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±¾²©Ê¿¿ÎÌâÏîÄ¿Ãû³ÆΪ£º Novel switchable spin-crossover complexes-based materials for molecular electronics
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Novel switchable spin-crossover complexes-based materials for molecular electronics

Molecular switches, which can undergo reversible changes of their electronic properties under external perturbation are attracting strong research interests because of their potential application in molecule-based nanodevices. In particular, magnetic switches, such as spin-crossover, charge-transfer complexes, whose spin-state can be controlled by light, pressure, temperature, electric and magnetic fields, open opportunities molecular electronic. In this context, strong efforts have been devoted to the deposition of these complexes onto solid surfaces as this can represent a first stage in the device¡¯s construction. However, most of the explored routes lead to isolating materials that are difficult to integrate into actual devices. Inspired by the devolvement of molecular electronic driven by polymer science, we started to explore new route that could lead to materials combining both the unusual electronic properties of the molecular switches and the advantageous conductive and mechanical properties of organic polymers.

Following some unprecedented results that have to be confirmed, this multidisciplinary PhD deals with the design, the synthesis and the characterization of a novel series of functionalized magnetic spin crossover complexes (SCO) ¨C based molecular switches incorporated into polymer matrices. The student will have several objectives, from their synthesis to their integration into hybrid nanomaterials. To achieve this challenging subject, several synthetic and complementary characterization techniques will be needed, including NMR and usual spectroscopies, cyclic voltammetry, DSC and ATG, as well as SQUID and PM-IRRAS to characterize their photoswitchable and magnetic properties. The ultimate goal is to elaborate robust switchable hybrid thin-films that aims to be integrated into electronic devices. This means also that thin film morphology preparation and characterization by AFM and/or XPS or even synchrotron measurements (XAS, XMCD) will also be necessary. This work will be co-directed by R. Lescouëzec and D. Kreher from IPCM, in close cooperation with other colleagues from Sorbonne University.


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