Polymer-Surfactant Interactions
Aqueous Chemistry of Laundry Detergents
Summary
This thesis describes a study of the interactions between surfactants and water-soluble polymers carrying
hydrophobic end groups, with a focus on liquid laundry detergents. The research topics can be subdivided
in two main themes. Interactions between hydrophobically-modified polymers and surfactant monomers,
micelles and vesicles in dilute aqueous solutions are described in Chapters 2 and 3. The surfactant
concentrations studied were in the range of 0 to 10 mM, which is quite typical for wash conditions. The
second main theme comprises the microstructure and rheology of concentrated structured liquid laundry
detergents with added hydrophobically-single-end-capped poly(sodium acrylate)s; Chapters 4 and 5.
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